Synthesis of amine-borane intramolecular complexes through palladium-catalyzed rearrangement of ammonioalkynyltriarylborates
Synthesis of amine-borane intramolecular complexes through palladium-catalyzed rearrangement of ammonioalkynyltriarylborates
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DOI：
10.1021/ol8001305
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发表时间：
2008-03-20
期刊：
影响因子：
5.2
通讯作者：
Murakami, Masahiro
中科院分区：
文献类型：
--
作者：
Ishida, Naoki;Narumi, Mizuna;Murakami, Masahiro
具有叔铵部分的炔基三芳基硼酸酯的钯催化重排反应立体选择性地产生胺-硼烷分子内配合物，其中一些表现出明显强的荧光。
The palladium-catalyzed rearrangement reaction of alkynyltriarylborates having a tertiary ammonium moiety stereoselectively afforded amine-borane intramolecular complexes, some of which exhibited significantly strong fluorescence.