High-pressure single-crystal x-ray diffraction study of two spin-crossover iron(II) complexes: Fe(Phen)2(NCS)2 and Fe(Btz)2(NCS)2
High-pressure single-crystal x-ray diffraction study of two spin-crossover iron(II) complexes: Fe(Phen)2(NCS)2 and Fe(Btz)2(NCS)2
复制标题
两种自旋交叉铁(II)络合物：Fe(Phen)2(NCS)2 和 Fe(Btz)2(NCS)2 的高压单晶 X 射线衍射研究
DOI：
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发表时间：
1993
期刊：
影响因子：
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通讯作者：
J. Zarembowitch
中科院分区：
文献类型：
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作者：
T. Granier;B. Gallois;J. Gaultier;J. Real;J. Zarembowitch
Crystal structures of Fe(Phen) 2 (NCS) 2 , form II (phen=1,10-phenanthroline) and Fe(Btz) 2 (NCS) 2 (Btz=2,2'-bi-4,5-dihydrothiazine) were determined at room temperature by X-ray diffraction, under a pressure of P≃1.0 GPa. For both compounds, the space group is orthorhombic, Pbcn (Z=4). Lattice constants of Fe(Phen) 2 (NCS) 2 are a=12.656(3), b=9.848(2), and c=16.597(4) A. Data were refined (159 parameters) to R w =0.043 for 631 observed reflections (F 0 >4σ(F 0)); for Fe(Brz) 2 (NCS) 2 , a=12.839(4), b=10.454(3), and c=16.362(4) A, with R w =0.056 (154 parameters for 662 observed reflections)
