Synthesis of benzimidazoles via iridium-catalyzed acceptorless dehydrogenative coupling
Synthesis of benzimidazoles via iridium-catalyzed acceptorless dehydrogenative coupling
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铱催化无受体脱氢偶联合成苯并咪唑
DOI：
10.1039/c5ob00904a
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发表时间：
2015-01-01
影响因子：
3.2
通讯作者：
Yan, Ming
中科院分区：
文献类型：
--
作者：
Sun, Xiang;Lv, Xiao-Hui;Yan, Ming
发展了一种在Ir催化下叔胺和芳胺的无受体脱氢偶联反应。以良好的产率合成了许多苯并咪唑类化合物。提出了一种Ir介导的C-H活化机制。这一发现为苯并咪唑的合成提供了一种新的策略。
Iridium-catalyzed acceptorless dehydrogenative coupling of tertiary amines and arylamines has been developed. A number of benzimidazoles were prepared in good yields. An iridium-mediated C-H activation mechanism is suggested. This finding represents a novel strategy for the synthesis of benzimidazoles.