LASER RAMAN-SCATTERING OF GLUCOSAMINE N-ACETYLGLUCOSAMINE, AND GLUCURONIC ACID

LASER RAMAN-SCATTERING OF GLUCOSAMINE N-ACETYLGLUCOSAMINE, AND GLUCURONIC ACID
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DOI:
10.1016/0304-4165(74)90196-2
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发表时间:
1974-01-01
期刊:
BIOCHIMICA ET BIOPHYSICA ACTA
影响因子:
--
通讯作者:
TU, AT
TU, AT
中科院分区:
其他
文献类型:
--
作者:
SHE, CY;TU, AT

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获得了α-D-葡萄糖、D-氨基葡萄糖盐酸盐、N-乙酰基-D-氨基葡萄糖和D-葡萄糖醛酸的激光拉曼光谱。氘交换结果的基础上,确定了来自O-OH和N-OH官能团的振动。通过比较α-d-葡萄糖、d-葡萄糖醛酸、d-氨基葡萄糖· HCl和N-乙酰基-d-α-氨基葡萄糖的光谱,还鉴别出了由β-COOH、β-CH 2-、β-NH3+和= NH基团引起的振动。
Laser Raman spectra of α-d-glucose, D-glucosamine· HCl, N-acetyl-d-glucosamine and d-glucuronic acid were obtained. The vibrations originating from O H and N H functional groups were identified on the basis of the deuterium exchange results. By comparing the spectra of α-d-glucose, d-glucuronic acid, d-glucosamine· HCl, and N-acetyl-d-α-glucosamine, the vibrations due to COOH, CH 2, NH 3+, and= NH groups were also identified.