A non-vacuum solution route to prepare amorphous metal oxides thin films for Cu2ZnSn(S,Se)4 solar cells

A non-vacuum solution route to prepare amorphous metal oxides thin films for Cu2ZnSn(S,Se)4 solar cells
复制标题

一种制备 Cu2ZnSn(S,Se)4 太阳能电池非晶金属氧化物薄膜的非真空溶液路线

DOI:
10.1016/j.jallcom.2016.11.333
复制
发表时间:
2017-02
影响因子:
6.2
通讯作者:
Yongzheng Fang
Yongzheng Fang
中科院分区:
材料科学2区
文献类型:
--
作者:
Yufeng Liu;Xinfeng Zheng;Qianqian Li;Mengqiu Long;Jingshan Hou;Na Zhang;Guoying Zhao;Yongzheng Fang

文献摘要

参考文献

被引文献

相似文献

提出了一种制备Cu_2ZnSn(S,Se)_4(CZTSSe)吸收体的非真空溶液法。在不加热和真空的条件下,通过将乙酸铜(II)、乙酸锌(II)和氯化锡(IV)溶解在乙醇溶液中来制备安全的不含硫和硒的前驱体溶液。采用旋涂法制备了非晶态金属氧化物薄膜。通过对非晶态金属氧化物薄膜进行硫化和硒化处理,得到了致密、致密、结晶性好、晶粒大的CZTSSe薄膜。采用玻璃/Mo/CZTSSe/CdS/i-ZnO/Al掺杂氧化锌(AZO)/Ag结构制备了CZTSSe薄膜太阳能电池,其能量转换效率为4.8 ± 0.5%。该方法为通过对无毒、稳定的非晶态金属氧化物薄膜进行硫化和硒化来获得高功率转换效率的CZTSSe薄膜太阳能电池提供了一种新的思路。
A facile non-vacuum solution route is proposed to fabricate Cu2ZnSn(S,Se)4(CZTSSe) absorbers. The secure sulfur and selenium-free precursor solution was prepared by dissolving copper (II) acetate, zinc acetate (II) and tin (IV) chloride in ethanol solution without the conditions of heating and vacuum. An amorphous metal oxides thin film was obtained by spin coating method. Dense and compact CZTSSe thin film with good crystallization and large grains formed by sulfurizing and selenizing the amorphous metal oxides thin film. CZTSSe thin film solar cells with a power conversion efficiency of 4.8 ± 0.5% were fabricated with the structure glass/Mo/CZTSSe/CdS/i-ZnO/Al-doped zinc oxide (AZO)/Ag. The method provides a novel thought to acquire high power conversion efficiency CZTSSe thin film solar cellsviasulfurizing and selenizing non-toxic and stable amorphous metal oxides thin films.
DOI: 10.1021/cm2002836
发表时间: 2011-05-24
影响因子: 8.6
作者:
Ford, Grayson M.;Guo, Qijie;Hillhouse, Hugh W.
通讯作者: Hillhouse, Hugh W.
DOI: 10.1002/aenm.201300712
发表时间: 2014
影响因子: 27.8
作者:
W. Yin;Yelong Wu;S. Wei;R. Noufi;M. Al‐Jassim;Yanfa Yan
通讯作者: W. Yin;Yelong Wu;S. Wei;R. Noufi;M. Al‐Jassim;Yanfa Yan
DOI: 10.1021/ja108427b
发表时间: 2010-12-15
影响因子: 15
作者:
Guo, Qijie;Ford, Grayson M.;Agrawal, Rakesh
通讯作者: Agrawal, Rakesh
DOI: 10.1016/j.solmat.2013.09.043
发表时间: 2014
影响因子: 6.9
作者:
G. Kaune;S. Hartnauer;F. Syrowatka;R. Scheer
通讯作者: G. Kaune;S. Hartnauer;F. Syrowatka;R. Scheer
DOI: 10.1039/c1ee02314d
发表时间: 2012
影响因子: 32.5
作者:
Kyoohee Woo;Youngwoo Kim;Jooho Moon
通讯作者: Kyoohee Woo;Youngwoo Kim;Jooho Moon