Morphology-Dependent Interactions of ZnO with Cu Nanoparticles at the Materials' Interface in Selective Hydrogenation of CO2 to CH3OH
Morphology-Dependent Interactions of ZnO with Cu Nanoparticles at the Materials' Interface in Selective Hydrogenation of CO2 to CH3OH
复制标题
CO2 选择性加氢成 CH3OH 过程中 ZnO 与 Cu 纳米粒子在材料界面处的形态依赖性相互作用
DOI：
10.1002/anie.201007108
复制
发表时间：
2011-01-01
影响因子：
16.6
通讯作者：
Tsang, Shik C.
中科院分区：
文献类型：
--
作者：
Liao, Fenglin;Huang, Yaqun;Tsang, Shik C.
近年来，二氧化碳（CO2）作为主要的温室气体，其排放对气候变化问题的影响越来越引起人们的关注。[1]目前正在考虑各种减少二氧化碳的固碳技术。最近已经证明，氢气可以从可再生能源，包括太阳能，水力发电和生物质大规模生产。[2]因此，通过将CO2氢化为高能量密度液体燃料而将其完全或部分再循环似乎是一种非常有吸引力的方法。因此，催化CO2加氢反应生成甲醇、高级醇、汽油和相关高级烃（类费托反应）重新受到关注。特别是，重点是甲醇的生产，这是目前燃料和化学基础设施的关键平台化学品。[3]最近对这种新的绿色工艺的经济可行性的评估支持这种可能性。[4]今天，甲醇是由含有CO和CO2（来自化石燃料）的合成气在Cu/ZnO/Al2O3催化剂上工业生产的。[5，6]这些Cu/ZnO基体系也被评价为用于CO2直接氢化的最有效的催化剂[方程式10.1]。①]。[7]尽管这两种反应
In recent years, carbon dioxide (CO2) has become the focus of much attention because of the position of CO2 as the primary greenhouse gas and the implication of its emissions on the problem of climate change.[1] Various sequestration technologies for CO2 abatement are being considered. It has been recently demonstrated that hydrogen gas can be manufactured on large scales from renewable sources, including solar energy, hydropower, and biomass.[2] Thus, complete or partial recycling of CO2 through its hydrogenation to high-energydensity liquid fuels appears to be a very attractive approach. As a result, catalytic CO2 hydrogenation reactions to methanol, higher alcohols, gasoline, and related higher hydrocarbons (Fischer–Tropsch-like reactions) have been receiving much renewed attention. Particularly, the focus is on the production of methanol, which is a key platform chemical for present fuel and chemical infrastructures.[3] A recent assessment of economic feasibility for this new green process supports the possibility.[4]Today, methanol is produced industrially from syngas containing CO and CO2 (derived from fossil fuels) over Cu/ZnO/Al2O3 catalysts.[5, 6] These Cu/ZnO based systems are also evaluated to be the most efficient catalysts for the direct hydrogenation of CO2 [Eq.(1)].[7] Although the two reactions