Donors for Organic Metals: Molecular Aspects
Donors for Organic Metals: Molecular Aspects
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有机金属供体：分子方面
DOI：
10.1002/ijch.198600045
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发表时间：
1986
影响因子：
3.2
通讯作者：
Gerald P. Ceasar
中科院分区：
文献类型：
--
作者：
D. Sandman;Gerald P. Ceasar
讨论了与对合成未知化合物作为有机金属前体感兴趣的化学家相关的物理化学问题。分子主题的强调，物理和结构的概念，激发合成活性的卤素化学，并在硒和碲系统的新成果进行了总结。提出了基于多烯和多并苯的两种给体分子结构的模型表示，并讨论了已知的例子。气相垂直电离电位和溶液电化学氧化还原电位之间的定量相关性研究使用有机金属的感兴趣的捐助者作为数据。这种相关性和这些缺点的后果的限制。最后，其中几个主题的未来可能的方向。
Physicochemical issues are discussed which are relevant to chemists interested in the synthesis of unknown compounds to serve as precursors to organic metals. Molecular topics are emphasized, physical and structural concepts which motivate synthetic activity in chalogen chemistry are presented, and new results in selenium and tellurium systems are summarized. Two model representations for donor molecular structures based on polyenes and polyacenes are presented and known examples are discussed. Quantitative correlations between gas phase vertical ionization potential and solution electrochemical redox potential are examined using donors of interest for organic metals as data. Limitations of such correlations and consequences of these shortcomings are given. Finally, possible future directions for several of these topics are posed.