SYNTHESIS AND CHIRAL RECOGNITION OF NOVEL CROWN ETHERS INCORPORATING HELICENE CHIRAL CENTERS
SYNTHESIS AND CHIRAL RECOGNITION OF NOVEL CROWN ETHERS INCORPORATING HELICENE CHIRAL CENTERS
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DOI：
10.1039/c39830000787
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发表时间：
1983-01-01
影响因子：
--
通讯作者：
OKAMOTO, Y
中科院分区：
文献类型：
--
作者：
NAKAZAKI, M;YAMAMOTO, K;OKAMOTO, Y
合成了两种新的含螺烯骨架的光学活性冠醚（7）和（14），并研究了它们的手性识别性能，结果表明（M）-（-）-（7）和（M）-（-）-（14）对苯甘氨酸甲酯和1-苯乙胺的手性识别作用相反。
Two novel optically active crown ethers (7) and (14) incorporating helicene molecular frameworks were prepared, and their chiral recognition properties were examined to show that (M)-(–)-(7) and (M)-(–)-(14) had opposite chiral recognition for the transport of methyl phenylglycinate or 1-phenylethylamine.