Non-metathesis reactions of ruthenium carbene catalysts and their application to the synthesis of nitrogen-containing heterocycles
Non-metathesis reactions of ruthenium carbene catalysts and their application to the synthesis of nitrogen-containing heterocycles
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DOI：
10.1002/tcr.20121
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发表时间：
2007-01-01
期刊：
影响因子：
6.6
通讯作者：
Nishida, Atsushi
中科院分区：
文献类型：
--
作者：
Arisawa, Mitsuhiro;Terada, Yukiyoshi;Nishida, Atsushi
综述了烯烃异构化、加氢、自由基反应、硅烷活化、环丙烷化、外映化、[3 + 2]环加成和环异构化等非甲基化反应。用烯烃异构化和随后的合环复分解合成吲哚，用环异构化合成吲哚，以及用环异构化作为关键步骤合成拳头素的推定结构，证明了这些反应的效用。(c) 2007日本化学期刊论坛和Wiley期刊公司。
Non-metathesis reactions of ruthenium carbene catalysts, such as olefin isomerization, hydrogenation, radical reaction, activation of silane, cyclopropanation, epimerization cocyclopropane, [3 + 2] cycloaddition, and cycloisomerization, are summarized. The utility of these reactions was demonstrated by the synthesis of indole using olefin isomerization and subsequent ring-closing metathesis, the synthesis of indoline using cycloisomerization, and the synthesis of the putative structure of fistulosin using cycloisomerization as a key step. (c) 2007 The Japan Chemical Journal Forum and Wiley Periodicals, Inc.