[2 + 3]Cycloaddition Reaction of a Kinetically Stabilized Distibene with a Nitrile Oxide Leading to the Formation of a Unique Heterocyclic Compound.
[2 + 3]Cycloaddition Reaction of a Kinetically Stabilized Distibene with a Nitrile Oxide Leading to the Formation of a Unique Heterocyclic Compound.
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[2 3]动力学稳定的二苯乙烯与氧化腈的环加成反应导致形成独特的杂环化合物。
DOI：
10.1002/chin.200740172
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发表时间：
2007
期刊：
影响因子：
--
通讯作者：
N. Tokitoh
中科院分区：
文献类型：
--
作者：
T. Sasamori;E. Mieda;Noriyoshi Nagahora;N. Tokitoh
通过动力学稳定的二苯乙烯BbtSb=SbBbt（Bbt = 2，6-双[双（三甲基硅基）甲基]-4-[三（三甲基硅基）甲基]苯基）与MesCNO（Mes =均三甲苯）的[2+3]环加成反应合成了1-氧杂-5-氮杂-2，3-二双环戊二烯-4-烯衍生物。
The synthesis of a 1-oxa-5-aza-2,3-distibacyclopent-4-ene derivative by the [2+3]cycloaddition reaction of a kinetically stabilized distibene, BbtSb=SbBbt (Bbt = 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris-(trimethylsilyl)methyl]phenyl), with MesCNO (Mes = mesityl) has been performed.