Vacuum ultraviolet radiation for single-photoionization mass spectrometry: A review

Vacuum ultraviolet radiation for single-photoionization mass spectrometry: A review
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DOI:
10.1006/mchj.1999.1745
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发表时间:
1999-07-01
影响因子:
4.8
通讯作者:
Butcher, DJ
Butcher, DJ
中科院分区:
化学2区
文献类型:
--
作者:
Butcher, DJ

文献摘要

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真空紫外(VU)辐射可用于执行单光电离(SPI)质谱(MS)。使用真空紫外线的优点包括它的应用程序与电离电位低于10.5电子伏特的所有化合物,它不能消除背景气体,和最小的离子碎片相比,大多数其他电离方法。本文综述了真空紫外SPI-MS在分析化学中的应用。真空紫外线生产的理论方面进行了讨论,沿着与实验安排。还包括真空紫外灯的建造和生产的实际提示。介绍了SPI质谱的一些实例,并沿着总结了该技术的应用。(C)北京:科学出版社.
Vacuum ultraviolet (VU) radiation may be employed to perform single-photoionization (SPI) mass spectrometry (MS). Advantages of the use of VUV include its application to all compounds with ionization potentials below 10.5 eV, its inability to ionize background gases, and minimal ion fragmentation compared to most other ionization methods. This paper is a review of the use of VUV for SPI-MS in analytical chemistry. Theoretical aspects of the production of VUV are discussed, along with experimental arrangements. Practical hints on the construction and production of VUV light are also included. Some examples of SPI mass spectra are presented, along with a summary of applications of this technique. (C) 1999 Academic Press.