The Development of Aza-Pinacol and Aza-Semipinacol Rearrangements for the Synthesis of Nitrogen-Containing Molecules
The Development of Aza-Pinacol and Aza-Semipinacol Rearrangements for the Synthesis of Nitrogen-Containing Molecules
复制标题
氮杂频哪醇和氮杂半频那醇重排合成含氮分子的进展
DOI：
10.1055/s-0035-1561385
复制
发表时间：
2016-02
期刊：
影响因子：
2
通讯作者：
Zu, Liansuo
中科院分区：
文献类型：
--
作者：
Yu, Yuanyuan;Li, Guang;Zu, Liansuo
摘要虽然氮杂频哪醇和氮杂半频哪醇重排作为合成方法的广泛应用尚未发现，但这些合成转化为含氮杂环化合物和天然生物碱的制备提供了新的策略。在此，我们简要地讨论了在这一领域的最新发展，并提出了我们的策略的基础上氮杂频哪醇重排的吲哚啉和吲哚啉的合成。1引言2最近开发的氮杂-频哪醇和氮杂-半频哪醇重排3吲哚啉/吲哚啉合成采用氮杂-频哪醇重排作为关键策略4结论
Abstract Although the widespread usage of aza-pinacol and aza-semipinacol rearrangements as synthetic methods has not been found, these synthetic transformations offer novel tactics for the preparation of nitrogen-containing heterocycles and natural alkaloids. Herein, we briefly discuss the most recent developments in this area and present our strategy based on aza-pinacol rearrangements for the synthesis of indolines and indolenines. 1 Introduction 2 Recently Developed Aza-Pinacol and Aza-Semipinacol Rearrangements 3 Indoline/Indolenine Synthesis Employing Aza-Pinacol Rearrangements as the Key Strategy 4 Conclusion