Fine tuning of the orifice size of an open-cage fullerene by placing selenium in the rim: insertion/release of molecular hydrogen
Fine tuning of the orifice size of an open-cage fullerene by placing selenium in the rim: insertion/release of molecular hydrogen
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DOI：
10.1039/b616478a
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发表时间：
2007-01-01
影响因子：
4.9
通讯作者：
Komatsu, Koichi
中科院分区：
文献类型：
--
作者：
Chuang, Shih-Ching;Murata, Yasujiro;Komatsu, Koichi
一种新合成的开笼富勒烯，在13元环孔的边缘含有硒，允许较温和的条件下插入氢，氢释放速率约为100%。比硫类似物快三倍
A newly synthesized open-cage fullerene containing selenium in the rim of the 13-membered-ring orifice allows milder conditions for hydrogen insertion, and the rate for hydrogen release is ca. three times faster than its sulfur analogue.