Design and Synthesis of a Novel Cyclophane as Host for Biologically Relevant Phosphates
Design and Synthesis of a Novel Cyclophane as Host for Biologically Relevant Phosphates
复制标题
作为生物相关磷酸盐主体的新型环烷的设计与合成
DOI：
10.3987/com-03-9756
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发表时间：
2003
期刊：
影响因子：
0.6
通讯作者：
Muneharu Miyake
中科院分区：
文献类型：
--
作者：
K. Metori;Muneharu Miyake
合成了一种新的水溶性环芳，其烷基链上带有4-二甲氨基吡啶基团，作为6 H，12 H-5，11-亚甲基二苯并-[B，f][1，5]二氮杂环辛四烯骨架的过渡基团，以研究其作为大环酶模型结合生物相关磷酸盐的能力。
A novel water-soluble cyclophane bearing 4-dimethylamino-pyridinium groups on the alkyl chains as blanches of 6H,12H-5,11-methanodibenzo-[b,f][1,5]diazocine skeleton was synthesized in order to investigate the ability as macrocyclic enzyme models to incorporate biologically relevant phosphates.