Electronic and steric impact of bis-NHC ligands on reactions of Pt3S2 cores in trinuclear complexes bearing bis-NHC ligands with various lengths of alkylene bridges
Electronic and steric impact of bis-NHC ligands on reactions of Pt3S2 cores in trinuclear complexes bearing bis-NHC ligands with various lengths of alkylene bridges
复制标题
双 NHC 配体对带有不同长度亚烷基桥双 NHC 配体的三核配合物中 Pt3S2 核反应的电子和空间影响
DOI：
10.1039/d1dt02747f
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发表时间：
2021
期刊：
影响因子：
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通讯作者：
Hiroshi Nakajima and Takanori Nishioka
中科院分区：
文献类型：
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作者：
Natsuki Yabune;Hiroshi Nakajima and Takanori Nishioka
亚烷基桥联的双-N-杂环卡宾配体作为强σ-给体增强了三铂配合物中Pt 3S 2核的反应性。尽管Ag（I）离子可能与Pt-Pt键反应，但由于配体的空间位阻，其中一个硫醚配体与Ag（I）离子配位。
Alkylene-bridged bis-N-heterocyclic carbene ligands working as strong σ-donors enhance the reactivity of the Pt3S2 core in a triplatinum complex. Although an Ag(I) ion possibly reacts with the Pt–Pt bond, one of the sulfide ligands coordinates to an Ag(I) ion due to the steric hindrance of the ligands.