Synthesis of Benzene-centered Trinuclear Phthalocyanines by Triple-click Chemistry
Synthesis of Benzene-centered Trinuclear Phthalocyanines by Triple-click Chemistry
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DOI：
10.1246/cl.2010.337
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发表时间：
2010-04-05
影响因子：
1.6
通讯作者：
Shibata, Norio
中科院分区：
文献类型：
--
作者：
Das, Banibrata;Umeda, Masashi;Shibata, Norio
我们在这里公开的合成新的苯为中心的三氟乙氧基涂层的三核Pc 1和它的非氟化类似物2与灵活的点击间隔。紫外-可见光谱研究表明，三氟乙氧基涂层可以导致在没有刚性间隔或任何外部来源的帮助下，在纯粹的非聚集，风车状分子结构的1。
We disclose here the synthesis of novel benzene-centered trifluoroethoxy-coated trinuclear Pc 1 and its nonfluorinated analog 2 with flexible click spacers. UV-vis study reveals that trifluoroethoxy coating can result in the purely nonaggregated, windmill-like molecular structure of 1 without rigid spacers or any external source of help.