Synthetic design of functional boron imidazolate frameworks

Synthetic design of functional boron imidazolate frameworks
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功能性硼咪唑骨架的合成设计

DOI:
10.1016/j.ccr.2015.08.003
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发表时间:
2016-01
影响因子:
20.6
通讯作者:
Zhang, Jian
Zhang, Jian
中科院分区:
化学1区
文献类型:
--
作者:
Zhang, Hai-Xia;Liu, Meng;Wen, Tian;Zhang, Jian

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硼咪唑骨架(BIF)是一类金属有机骨架(MOF),它是通过金属阳离子使预定的硼咪唑配合物发生交联而形成的。BIF的一个基本特征是,在溶剂热合成之前,三连接的三脚架和四连接的四面体配体都可以很容易地合成。在这篇综述中,我们重点介绍了具有沸型和其他类型的基于三连接或四连接的咪唑硼酸配体的拓扑网络的生物IF的最新进展。特别是,我们强调了合成方法学的基本设计原则,以构建具体的拓扑BIF,特别是针对沸石拓扑。
Boron imidazolate frameworks (BIFs) are a family of metal–organic frameworks (MOFs) that based on the cross-linking of predetermined boron-imidazolate complexes by metal cations. One fundamental feature of BIFs is that both three-connected tripodal liangds and four-connected tetrahedral ligands can be readily synthesized prior to solvothermal synthesis. In this review, we focus on the recent advances in BIFs that possess zeotype and other types of topological nets based on the three- or four- connected boron imidazolate ligands. In particular, we emphasize the basic design principles of the synthetic methodology to construct specifically topological BIFs, especially, towards the zeolitic topologies.
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