The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold
The Role of Metal Hydroxide Complexes in Late Transition Metal-Mediated Transmetalation Reaction: The Case of Gold
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DOI：
10.1002/adsc.201200233
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发表时间：
2012-09-01
影响因子：
5.4
通讯作者：
Nolan, Steven P.
中科院分区：
文献类型：
--
作者：
Dupuy, Stephanie;Crawford, Luke;Nolan, Steven P.
在金化学中，当与硼酸反应时，观察到金属中心的氢氧化物功能作为一种有效的金属转化基促进剂，导致金-芳基键的极快形成。
In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold-aryl bonds.