Development and mechanism of an enantioselective bromocycloetherification reaction via Lewis base/chiral Brønsted acid cooperative catalysis.
Development and mechanism of an enantioselective bromocycloetherification reaction via Lewis base/chiral Brønsted acid cooperative catalysis.
复制标题
通过刘易斯碱/手性布朗斯特酸合作催化的对映体选择性溴环蛋白化反应的开发和机制。
作者：
Denmark SE;Burk MT
详细介绍了由非手性刘易斯碱和手性布朗斯特酸组成的溴代环醚化二元催化剂体系的开发。初步动力学研究的结果也被提出。
The development of a binary catalyst system for bromocycloetherification, consisting of an achiral Lewis base and a chiral Brønsted acid, is described in detail. The results of preliminary kinetic studies are also presented.