A Simple Graphical Method to Determine the Order in Catalyst.

A Simple Graphical Method to Determine the Order in Catalyst.
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DOI:
10.1002/anie.201508983
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发表时间:
2016-02-05
期刊:
Angewandte Chemie (International ed. in English)
影响因子:
--
通讯作者:
Burés J
Burés J
中科院分区:
其他
文献类型:
--
作者:
Burés J

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提出了一种图解分析方法来说明催化剂中的顺序。该分析使用标准化的时间尺度t [cat] t n来调整用浓度数据构建的整个反应曲线。该方法操作简单快速,因为它直接使用浓度数据,因此避免了通常提取速率所需的数据处理。与使用速率的方法相比,标准化时间尺度分析需要较少的实验,并通过使用整个反应剖面的信息将实验误差的影响降至最低。
A graphical analysis to elucidate the order in catalyst is presented. This analysis uses a normalized time scale, t [cat]T n, to adjust entire reaction profiles constructed with concentration data. The method is fast and simple to perform because it directly uses the concentration data, therefore avoiding the data handling that is usually required to extract rates. Compared to methods that use rates, the normalized time scale analysis requires fewer experiments and minimizes the effects of experimental errors by using information on the entire reaction profile.