[2](1,3)Adamantano[2](2,7)pyrenophane: A Hydrocarbon with a Large Dipole Moment.
[2](1,3)Adamantano[2](2,7)pyrenophane: A Hydrocarbon with a Large Dipole Moment.
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DOI：
10.1002/anie.201602201
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发表时间：
2016-08
影响因子：
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通讯作者：
Paul Kahl;J. Wagner;C. Balestrieri;Jonathan Becker;H. Hausmann;G. Bodwell;P. Schreiner
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文献类型：
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作者：
Paul Kahl;J. Wagner;C. Balestrieri;Jonathan Becker;H. Hausmann;G. Bodwell;P. Schreiner
sp(3)杂化的亲本金刚烷与sp(2)杂化的芘发生融合，形成具有很大偶极矩的杂化结构，该偶极矩是由芘部分弯曲引起的。本文介绍了这种新型化合物的合成、电子性质、光学性质和动力学行为的研究。
The fusion of the sp(3) -hybridized parent diamondoid adamantane with the sp(2) -hybridized pyrene results in a hybrid structure with a very large dipole moment which arises from bending the pyrene moiety. Presented herein is the synthesis, study of the electronic and optical properties, as well as the dynamic behavior of this new hydrocarbon.