Multi-step detection of cyanide ion by a bis(dimesitylboryl)dibenzoazaborine
Multi-step detection of cyanide ion by a bis(dimesitylboryl)dibenzoazaborine
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DOI：
10.1016/j.jorganchem.2009.07.046
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发表时间：
2009-11-01
影响因子：
2.3
通讯作者：
Kawashima, Takayuki
中科院分区：
文献类型：
--
作者：
Agou, Tomohiro;Sekine, Masaki;Kawashima, Takayuki
一种双(二甲基硼基)二苯并氮硼与多达两个氰离子以分步方式形成Lewis酸碱型络合物。尽管氟离子与硼原子的亲和力高于氰离子，但氰离子的络合形成常数大于氟离子。(C)2009爱思唯尔B.V.保留所有权利。
A bis(dimesitylboryl)dibenzoazaborine formed Lewis acid-base type complexes with up to two cyanide ions in stepwise fashion. The complex formation constants for cyanide ion were larger than those for fluoride ion, despite the higher affinity of fluoride ion to boron atoms than that of cyanide ion. (C) 2009 Elsevier B.V. All rights reserved.