The organocatalytic addition of bis(arylsulfonyl)methane to alpha,beta-unsaturated aldehydes and the synthesis of optically-enriched 3-methyl-alkanols.
The organocatalytic addition of bis(arylsulfonyl)methane to alpha,beta-unsaturated aldehydes and the synthesis of optically-enriched 3-methyl-alkanols.
复制标题
双(芳基磺酰基)甲烷与α,β-不饱和醛的有机催化加成以及光学富集的3-甲基烷醇的合成。
作者：
J. L. García Ruano;V. Marcos;J. Alemán
本发明提供了一种用于α，β-不饱和醛的β-甲基化的间接有机催化方法，该方法包括由脯氨醇衍生物催化的双（芳基磺酰基）甲烷的加成和变色磺酰基的进一步消除。
An indirect organocatalytic method for the beta-methylation of alpha,beta-unsaturated aldehydes that involves the addition of bis(arylsulfonyl)methane catalyzed by prolinol derivatives and further elimination of the chameleonic sulfonyl groups is presented.
DOI：
10.1021/jo049567e
发表时间：
2004-07
期刊：
The Journal of organic chemistry
影响因子：
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作者：
David R. Williams;A. Nold;R. Mullins
通讯作者：
David R. Williams;A. Nold;R. Mullins