Generation of substituted styrenes via Suzuki cross-coupling of aryl halides with 2,4,6-trivinylcyclotriboroxane

Generation of substituted styrenes via Suzuki cross-coupling of aryl halides with 2,4,6-trivinylcyclotriboroxane
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DOI:
10.1021/jo020074o
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发表时间:
2002-07-12
影响因子:
3.6
通讯作者:
O'Shea, DF
O'Shea, DF
中科院分区:
化学2区
文献类型:
--
作者:
Kerins, F;O'Shea, DF

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官能化苯乙烯衍生物的合成可以利用芳基卤化物和2,4,6-三乙烯基环三硼氧烷-吡啶络合物之间的Suzuki交叉偶联方案容易地实现。邻位取代的芳基卤化物的阵列的调查的程序的范围和局限性进行了论证。
The synthesis of functionalized styrene derivatives can be readily achieved utilizing a Suzuki cross-coupling protocol between aryl halides and 2,4,6-trivinylcyclotriboroxane-pyridine complex. The scope and limitations of the procedure were demonstrated by investigation of an array of ortho-substituted aryl halides.