Highly regio- and stereoselective intermolecular tandem reaction to synthesize chloro-substituted 1,3-butadienes.
Highly regio- and stereoselective intermolecular tandem reaction to synthesize chloro-substituted 1,3-butadienes.
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DOI：
10.1039/b923464k
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发表时间：
2010-02
影响因子：
4.9
通讯作者：
Jing‐Mei Huang;Yi Dong;Xu-Xiao Wang;Hui-Chao Luo
中科院分区：
文献类型：
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作者：
Jing‐Mei Huang;Yi Dong;Xu-Xiao Wang;Hui-Chao Luo
在钯催化下，炔、CuCl（2）和烯烃通过一系列氯钯化/Heck反应，高区域选择性和立体选择性地串联反应生成氯取代的1，3-二烯。
A palladium catalyzed highly regio- and stereoselective intermolecular tandem reaction of alkynes, CuCl(2) and alkenes by a sequence of chloropalladation/Heck reaction to produce chloro-substituted 1,3-dienes is achieved.