Near-infrared-induced electron transfer of an uranyl macrocyclic complex without energy transfer to dioxygen

Near-infrared-induced electron transfer of an uranyl macrocyclic complex without energy transfer to dioxygen
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DOI:
10.1039/c5cc00903k
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发表时间:
2015-01-01
影响因子:
4.9
通讯作者:
Fukuzumi, Shunichi
Fukuzumi, Shunichi
中科院分区:
化学2区
文献类型:
--
作者:
Davis, Christina M.;Ohkubo, Kei;Fukuzumi, Shunichi

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在电子给体和受体的存在下,铀酰大环化合物与环[1]呋喃[1]吡啶[4]-吡咯(1)的二氯甲烷溶液在近红外(NIR)波段(1177 Nm)被光激发,导致近红外诱导电子转移,而不通过能量转移产生单线态氧。
Photoexcitation of dichloromethane solutions of an uranyl macrocyclic complex with cyclo[1] furan[1] pyridine[4]-pyrrole (1) at the near-infrared (NIR) band (1177 nm) in the presence of electron donors and acceptors resulted in NIR-induced electron transfer without producing singlet oxygen via energy transfer.