The Solubilities of Hydrogen, Deuterium, and Helium in Molten Li2BeF4

The Solubilities of Hydrogen, Deuterium, and Helium in Molten Li2BeF4
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DOI:
10.1021/i160051a015
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发表时间:
1974-08
期刊:
Industrial & Engineering Chemistry Fundamentals
影响因子:
--
通讯作者:
A. Malinauskas;D. M. Richardson
A. Malinauskas;D. M. Richardson
中科院分区:
其他
文献类型:
--
作者:
A. Malinauskas;D. M. Richardson

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测量了H_2、D_2和He在熔融Li_2BeF_4中的溶解度。奥斯特瓦尔德系数Kc的值在773-1073 K温度范围内,对He测定的溶解态气体浓度与气相浓度的平衡比可由表达式log(103 KC)= log 7-(1177/7)-0.7954来描述,而在773-973 K的温度范围内,H2和D2的组合数据可以由表达式log(103 KC)= log 7-表示。
Solubilities of H2, D2, and He in molten Li2BeF4 have been measured. Values of the Ostwald coefficient Kc (equilibrium ratio of gas concentration in the dissolved state to the gas-phase concentration) which were determined for He can be described over the temperature range 773-1073 K by the expression log (103KC)= log 7—(1177/7)—0.7954, whereas the combined data for H2 and D2 can be represented over the temperature range 773-973 K by the expression log (103KC)= log 7—