Improved synthesis of trigone trimer cluster metal organic framework MIL-100Al by a later entry of methyl groups.
Improved synthesis of trigone trimer cluster metal organic framework MIL-100Al by a later entry of methyl groups.
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DOI：
10.1039/c5cc08450d
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发表时间：
2016-01
影响因子：
4.9
通讯作者：
Jiangfeng Yang;Jun Wang;S. Deng;Jinping Li
中科院分区：
文献类型：
--
作者：
Jiangfeng Yang;Jun Wang;S. Deng;Jinping Li
为经济地从H3BTC直接定向合成三角三聚体簇合物MIL-100Al，进行了甲基或乙基的后继加入。在DMF水溶液中得到了纯净的MIL-100Al相，其中等量的甲基和羧基是成功合成MIL-100Al的关键。
Later entry of methyl or ethyl groups was carried out for the economical synthesis of trigone trimer cluster MIL-100Al oriented from H3BTC directly. The pure phase MIL-100Al was obtained in a DMF aqueous solution, and equal amounts of methyl and carboxyl groups are the key for the successful synthesis of MIL-100Al.