Larger spontaneous polarization ferroelectric inorganic-organic hybrids: [PbI3](infinity) chains directed organic cations aggregation to Kagomé-shaped tubular architecture.
Larger spontaneous polarization ferroelectric inorganic-organic hybrids: [PbI3](infinity) chains directed organic cations aggregation to Kagomé-shaped tubular architecture.
复制标题
DOI：
10.1021/ja907562m
复制
发表时间：
2010-01
影响因子：
15
通讯作者：
Hai-Rong Zhao;Dong-ping Li;X. Ren;You Song;W. Jin
中科院分区：
文献类型：
--
作者：
Hai-Rong Zhao;Dong-ping Li;X. Ren;You Song;W. Jin
四种同结构无机-有机杂化铁电化合物，由非手性 3-R-亚苄基-1-氨基吡啶鎓（R = NO(2)、Br、Cl 或 F 分别代表 1-4）和 [PbI(3)](-) 阴离子组装而成，具有手性 Kagomé 形管状聚集结构，表现出更大的自发极化。
Four isostructural inorganic-organic hybrid ferroelectric compounds, assembled from achiral 3-R-benzylidene-1-aminopyridiniums (R = NO(2), Br, Cl, or F for 1-4, respectively) and [PbI(3)](-) anions with the chiral Kagomé-shaped tubular aggregating architecture, show larger spontaneous polarizations.