Tuning the Properties of Corannulene-Based Polycyclic Aromatic Hydrocarbons by Varying the Fusing Positions of Corannulene.
Tuning the Properties of Corannulene-Based Polycyclic Aromatic Hydrocarbons by Varying the Fusing Positions of Corannulene.
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DOI：
10.1021/acs.orglett.0c02754
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发表时间：
2020-09
期刊：
影响因子：
5.2
通讯作者：
Qi Xu;Chu Wang;Yu Zhao;Dan Zheng;Chengyuan Shao;Weijie Guo;Xuebin Deng;Ying Wang;Xuebo Chen;Jun Zhu;Hua Jiang
中科院分区：
文献类型：
--
作者：
Qi Xu;Chu Wang;Yu Zhao;Dan Zheng;Chengyuan Shao;Weijie Guo;Xuebin Deng;Ying Wang;Xuebo Chen;Jun Zhu;Hua Jiang
The selective fusions with pyrene derivative to the rim and flank bonds of corannulene generated 4 and 7, respectively, which underwent a Scholl reaction to provide novel distorted PAHs CORA-1 and CORA-2, consisting of corannulene and dibenzocoronene units with different connections between them. The studies revealed that the properties of these PAHs are highly dependent on the fusing positions of corannulene.
