Spin-site exchange system constructed from endohedral metallofullerenes and organic donors.
Spin-site exchange system constructed from endohedral metallofullerenes and organic donors.
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DOI：
10.1021/ja062634x
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发表时间：
2006-10
影响因子：
15
通讯作者：
T. Tsuchiya;Kumiko Sato;H. Kurihara;T. Wakahara;Y. Maeda;T. Akasaka;K. Ohkubo;S. Fukuzumi;Tatsuhisa Kato;S. Nagase
中科院分区：
文献类型：
--
作者：
T. Tsuchiya;Kumiko Sato;H. Kurihara;T. Wakahara;Y. Maeda;T. Akasaka;K. Ohkubo;S. Fukuzumi;Tatsuhisa Kato;S. Nagase
研究了顺磁性La@C82金属富勒烯与有机给体分子(D)在溶液中的络合行为。结果表明，La@C82与D通过电子转移形成1：1的络合物。La@C82和D与[La@C82]-/[D]*+在溶液中处于平衡状态，可以通过改变温度和溶剂来控制。
Complexation behavior of the paramagnetic La@C82 metallofullerene with organic donor molecules (D) in solution is investigated. It is revealed that La@C82 and D form a 1:1 complex as a result of electron transfer. La@C82 and D are in equilibrium with [La@C82]-/[D]*+ in solution, which is readily controllable by changing the temperature and solvent.