Changing Mixed-valence State of Hexacobalt Cluster by Substituting Central Metal Ion and by Electrochemical Reduction —Different Mixed-valence States of [M{Co(prolinato)2}6]4+ (M = Ba2+ and La3+)
Changing Mixed-valence State of Hexacobalt Cluster by Substituting Central Metal Ion and by Electrochemical Reduction —Different Mixed-valence States of [M{Co(prolinato)2}6]4+ (M = Ba2+ and La3+)
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DOI：
10.1246/cl.2005.300
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发表时间：
2005-03
影响因子：
1.6
通讯作者：
T. Komiyama;S. Igarashi;Yoshimasa Hoshino;Y. Yukawa
中科院分区：
文献类型：
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作者：
T. Komiyama;S. Igarashi;Yoshimasa Hoshino;Y. Yukawa
簇合物Ba{Co（prolinato）2}6和La{Co（prolinato）2}6由脯氨酸配体桥接，结晶为[M{Co（prolinato）2}6]（ClO 4）4。Ba{Co（pro）2}6团簇有两个CoIII和四个CoI。
Clusters, Ba{Co(prolinato)2}6 and La{Co(prolinato)2}6, which are bridged by prolinato ligands, were crystallized as [M{Co(prolinato)2}6](ClO4)4. The Ba{Co(pro)2}6 cluster has two CoIII and four CoI...