Remarkable oxidizing ability of triplet excited states of tetrazines produced by photosensitization with Ru(bPY)32+

Remarkable oxidizing ability of triplet excited states of tetrazines produced by photosensitization with Ru(bPY)32+
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DOI:
10.1039/b513110c
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发表时间:
2006-02-07
影响因子:
4.9
通讯作者:
Fukuzumi, S
Fukuzumi, S
中科院分区:
化学2区
文献类型:
--
作者:
Yuasa, J;Fukuzumi, S

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Ru(Bpy)(3)(2+)*(bpy=2,2‘-联吡啶,*代表激发态)与四嗪类化合物发生有效的能量转移,得到了比Ru(Bpy)(3)(2+)*更长的寿命和更强的氧化能力的三重态激发态。
An efficient energy transfer from Ru(bpy)(3) (2+)* (bpy = 2,2'-bipyridine, * denotes the excited state) to tetrazines occurs to yield the triplet excited states of tetrazines, which have much longer lifetimes and higher oxidizing ability as compared with those of Ru(bpy)(3)(2+)*.