Through-space ligand interactions in enantiomeric dinuclear Ru complexes.
Through-space ligand interactions in enantiomeric dinuclear Ru complexes.
复制标题
对映体双核钌配合物中的空间配体相互作用。
作者:
Nora Planas;G. Christian;Elena Mas;X. Sala;X. Fontrodona;F. Maseras;A. Llobet
Molecular twisting: A family of dinuclear Ru complexes of general formula [{Ru (T)(L)} 2 (μ-bpp)](n+ 1)+(T= tridentate meridional ligand; bpp= tetradentate bridging ligand and L= monodentate ligand, n= 1 or 2) have been prepared and thoroughly characterized. In solution these complexes display a global dynamic behavior in which the monodentate ligands undergo a synchronized twisting motion.(Figure Presented)© 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.