Tantalum-based bimetallic oxides deposited on spherical carbon of biological origin for use as counter electrodes in dye sensitized solar cells

Tantalum-based bimetallic oxides deposited on spherical carbon of biological origin for use as counter electrodes in dye sensitized solar cells
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沉积在生物来源的球形碳上的钽基双金属氧化物,用作染料敏化太阳能电池的对电极

DOI:
10.1016/j.electacta.2019.04.086
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发表时间:
2019-06
影响因子:
6.6
通讯作者:
Hou Yuzhi
Hou Yuzhi
中科院分区:
材料科学2区
文献类型:
--
作者:
Yun Sining;Zhou Xiao;Zhang Yangliang;Wang Chen;Hou Yuzhi

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Dye-sensitized solar cells (DSSCs) have attracted remarkable attention due to their high efficiency, environmentally friendly, and low cost. The counter electrode (CE) catalysts as an indispensable part play a crucial role in DSSCs. Herein, the novel tantalum-based bimetallic oxides (FeTa2O6, CoTa2O6, and CuTa10O26) and bio-based spherical carbon (SC) supported composites (FeTa2O6/SC, CoTa2O6/SC, and CuTa10O26/SC) were prepared successfully through a hydrothermal/annealing process, which were used as CEs catalysts for DSSCs. The bio-based SCs were obtained through hydrothermal carbonization of aloe peel waste. Of them, the FeTa2O6/SC, CoTa2O6/SC, and CuTa10O26/SC CEs catalysts exhibited excellent electrocatalytic activities and electrocatalytic stability for I3−reduction, thus resulted in comparable power conversion efficiency (PCE) of 6.85%, 6.79%, and 6.53% to Pt-based CE (6.34%) in DSSCs. This work will open new research opportunities for the use of transition metal compounds (TMCs) in renewable energy fields.
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