A modular flow reactor for performing Curtius rearrangements as a continuous flow process
A modular flow reactor for performing Curtius rearrangements as a continuous flow process
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DOI：
10.1039/b801631n
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发表时间：
2008-01-01
影响因子：
3.2
通讯作者：
Tierney, Jason P.
中科院分区：
文献类型：
--
作者：
Baumann, Marcus;Baxendale, Ian R.;Tierney, Jason P.
描述了在二苯基磷叠氮存在下，利用介流流动反应器进行羧酸的Curtius重排反应和捕获中间体异氰酸酯与各种亲核剂的反应。
The use of a mesofluidic flow reactor is described for performing Curtius rearrangement reactions of carboxylic acids in the presence of diphenylphosphoryl azide and trapping of the intermediate isocyanates with various nucleophiles.