A preliminary step toward molecular spring driven by cooperative guest binding
A preliminary step toward molecular spring driven by cooperative guest binding
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DOI：
10.1016/j.tetlet.2009.02.086
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发表时间：
2009-04-29
影响因子：
1.8
通讯作者：
Takeuchi, Masayuki
中科院分区：
文献类型：
--
作者：
Ikeda, Tomohiro;Shinkai, Seiji;Takeuchi, Masayuki
在1:6的化学计量中，合成了一个由两种不同的旋转单元组成的大环宿主分子，即cerum(IV) bis(porphyrinate)s和fenocenyl旋转单元，具有收缩/膨胀运动，可视为协同客体结合驱动的人工分子弹簧的原型。2009爱思唯尔有限公司版权所有。
A macrocyclic host molecule that comprised two different rotating modules, cerum(IV) bis(porphyrinate)s and fenocenyl rotating, units, exhibiting contraction/expansion motion was synthesized, which call be regarded as a prototype of artificial molecular spring driven by cooperative guest binding in 1:6 stoichiometry. (C) 2009 Elsevier Ltd. All rights reserved.