A new approach to highly conductive polymer electrolytes: synthesis of gelling fluoroalkylated end-capped 2-acrylamido-2-methylpropanesulfonic acid copolymers containing poly(oxyethylene) units
A new approach to highly conductive polymer electrolytes: synthesis of gelling fluoroalkylated end-capped 2-acrylamido-2-methylpropanesulfonic acid copolymers containing poly(oxyethylene) units
复制标题
高导电聚合物电解质的新方法：含聚氧乙烯单元的凝胶化氟烷基化封端2-丙烯酰胺-2-甲基丙磺酸共聚物的合成
DOI：
10.1016/s0014-3057(00)00024-0
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发表时间：
2000
影响因子：
6
通讯作者：
T. Kawase
中科院分区：
文献类型：
--
作者：
H. Sawada;Y. Ariyoshi;K. Lee;J. Kyokane;T. Kawase
以氟烷酰过氧化物为原料，制备了新型含聚氧乙烯基的端盖2-丙烯酰胺-2-甲基丙磺酸氟烷基化共聚物。结果表明，这些含氟共聚物在非交联条件下可以在DMSO中形成凝胶，并且这些含锂盐的含氟聚合物凝胶电解质在室温下具有10−3S/cm水平的相当高的离子电导率。
New fluoroalkylated end-capped 2-acrylamido-2-methylpropanesulfonic acid copolymers containing poly(oxyethylene) units were prepared by the use of fluoroalkanoyl peroxides. It was demonstrated that these fluorinated copolymers can form gels in DMSO under non-crosslinked conditions, and these fluorinated polymeric gelling electrolytes containing lithium salts exhibit a considerably high ionic conductivity of 10−3S/cm level at room temperature.