Oxygen-doped nanodiamonds: synthesis and functionalizations.
Oxygen-doped nanodiamonds: synthesis and functionalizations.
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氧掺杂纳米金刚石：合成和功能化。
DOI：
10.1021/ol901089h
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发表时间：
2009
期刊：
影响因子：
5.2
通讯作者：
P. Schreiner
中科院分区：
文献类型：
--
作者：
A. Fokin;T. Zhuk;A. Pashenko;Pavlo O. Dral;P. Gunchenko;J. Dahl;R. Carlson;Tatyana V. Koso;M. Serafin;P. Schreiner
代表一类新的碳纳米颗粒的恶二金刚烷类化合物是由相应的金刚烷酮类化合物通过有效的两步程序制备的，该两步程序涉及添加甲基碘化镁和在三氟乙酸中用三氟过氧乙酸氧化。oxacages的反应性是由掺杂剂的位置，并在良好的协议与计算预测。
Oxadiamondoids representing a new class of carbon nanoparticles were prepared from the respective diamondoid ketones via an effective two-step procedure involving addition of methyl magnesium iodide and oxidation with trifluoroperacetic acid in trifluoroacetic acid. The reactivities of the oxacages are determined by the position of the dopant and are in good agreement with computational predictions.