First observation of light-induced spin change in vacuum deposited thin films of iron spin crossover complexes.
First observation of light-induced spin change in vacuum deposited thin films of iron spin crossover complexes.
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DOI：
10.1039/c1dt10651a
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发表时间：
2011-06
影响因子：
4
通讯作者：
H. Naggert;A. Bannwarth;S. Chemnitz;T. von Hofe;E. Quandt;F. Tuczek
中科院分区：
文献类型：
--
作者：
H. Naggert;A. Bannwarth;S. Chemnitz;T. von Hofe;E. Quandt;F. Tuczek
采用真空沉积法制备了[Fe(H(2)Bpz)(2)(phen)](1)和[Fe(H(2)Bpz)(2)(bipy)](2)薄膜，并对其自旋交叉行为进行了研究。首次在这类体系中观察到光致激发自旋态捕获（LIESST）。薄膜中的T（1/2）和T（LIESST）与体积值一致。
Thin films of [Fe(H(2)Bpz)(2)(phen)] (1) and [Fe(H(2)Bpz)(2)(bipy)] (2) are prepared by vacuum deposition and investigated with respect to their spin crossover behaviour. For the first time light-induced excited spin state trapping (LIESST) is observed in such systems. T(1/2) and T(LIESST) in the films are in agreement with the bulk values.