Bis{μ-2-[1-(2-Pyridylmethyl-imino)eth-yl]phenolato}bis-[azido-copper(II)].
Bis{μ-2-[1-(2-Pyridylmethyl-imino)eth-yl]phenolato}bis-[azido-copper(II)].
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双{μ-2-[1-(2-吡啶基甲基-亚氨基)乙基]酚基}双-[叠氮基-铜(II)]。
DOI：
10.1107/s1600536809030475
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发表时间：
2009
期刊：
影响因子：
--
通讯作者：
Sun,Bai-Wang
中科院分区：
文献类型：
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作者：
Zhang,Jun;Chen,Xiao-Dan;Zhang,Huai-Hong;Sun,Bai-Wang
以Cu(NO3)2·3H2O与希夫碱2-[1-（2-吡啶基甲基）乙基]苯酚（HL）在甲醇-水溶液中，以NaN3为桥接配体合成了标题化合物[Cu2(C14H13N2O)2(N3)2]。不对称单元包含一半分子，另一半由反转中心生成。每个CuII原子呈现出轻微扭曲的三角锥体几何形状，由一个席夫碱配体的两个N原子和一个O原子、另一个席夫碱配体的另一个O原子和叠氮化物N原子组成。晶体结构由分子间的C-H⋯N氢键稳定。
The title compound, [Cu2(C14H13N2O)2(N3)2], was synthesized by the reaction of Cu(NO3)2·3H2O with the Schiff base 2-[1-(2-pyridylmethylimino)ethyl]phenol (HL) in methanol–water solution, adding NaN3 as the bridging ligand. The asymmetric unit contains one half-molecule, the other half being generated by the inversion center. Each CuII atom shows a slightly distorted trigonal-pyramidal geometry formed by two N atoms and one O atom from one Schiff base ligand, by another O atom of a second Schiff base ligand and by an azide N atom. The crystal structure is stabilized by intermolecular C—H⋯N hydrogen bonds.