Synthesis of stable and soluble one-handed helical poly(substituted acetylene)s without chiral pendant groups via polymer reaction in membrane state
Synthesis of stable and soluble one-handed helical poly(substituted acetylene)s without chiral pendant groups via polymer reaction in membrane state
复制标题
DOI：
10.1016/j.polymer.2012.03.022
复制
发表时间：
2012-05
期刊：
影响因子：
4.6
通讯作者：
Yunosuke Abe;T. Aoki;Hongge Jia;Shingo Hadano;Takeshi Namikoshi;Yuriko Kakihana;Lijia Liu;Y. Zang-Y.-Za
中科院分区：
文献类型：
--
作者：
Yunosuke Abe;T. Aoki;Hongge Jia;Shingo Hadano;Takeshi Namikoshi;Yuriko Kakihana;Lijia Liu;Y. Zang-Y.-Za
通过不对称引发聚合反应，合成了一种不含任何其它手性基团的单手螺旋共轭聚合物。成功的原因是聚合反应在膜状态下进行。这是一种获得这种独特的手性聚合物的替代方法，这是我们以前报道的仅通过螺旋-有义-选择性聚合（HSSP）获得的。此外，手性诱导的效率高于HSSP。有趣的是，“膜态”就像是一个保护基团。
A soluble and stable one-handed helical conjugated polymer without the coexistence of any other chiral moieties was successfully synthesized by asymmetric-induced polymerization of a chiral monomer having two hydroxyl groups followed by desubstitution of the chiral groups in a solid membrane state. The reason for the success was the polymer reaction was carried out in the membrane state. This is an alternative method to obtain such a unique chiral polymer which was obtained only by the helix-sense-selective polymerization (HSSP) we reported before. In addition the efficiency of the chiral induction was higher than that of the HSSP. It is interesting that the “Membrane state” acted like as if a protecting group.