Transition-Metal-Catalyzed Redox-Neutral and Redox-Green C-H Bond Functionalization
Transition-Metal-Catalyzed Redox-Neutral and Redox-Green C-H Bond Functionalization
复制标题
过渡金属催化的氧化还原中性和氧化还原绿色 C-H 键功能化
DOI：
10.1002/tcr.201500274
复制
发表时间：
2016
期刊：
影响因子：
6.6
通讯作者：
Huang Hanmin
中科院分区：
文献类型：
--
作者：
Wang Hongli;Huang Hanmin
Transition‐metal‐catalyzed C–H bond functionalization has become one of the most promising strategies to prepare complex molecules from simple precursors. However, the utilization of environmentally unfriendly oxidants in the oxidative C–H bond functionalization reactions reduces their potential applications in organic synthesis. This account describes our recent efforts in the development of a redox‐neutral C–H bond functionalization strategy for direct addition of inert C–H bonds to unsaturated double bonds and a redox‐green C–H bond functionalization strategy for realization of oxidative C–H functionalization with O2as the sole oxidant, aiming to circumvent the problems posed by utilizing environmentally unfriendly oxidants. In principle, these redox‐neutral and redox‐green strategies pave the way for establishing new environmentally benign transition‐metal‐catalyzed C–H bond functionalization strategies.
