Mild solvothermal syntheses and characterization of layered copper thioantimonates(III) and thioarsenate(III).
Mild solvothermal syntheses and characterization of layered copper thioantimonates(III) and thioarsenate(III).
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DOI：
10.1021/ic402864s
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发表时间：
2014-05
影响因子：
4.6
通讯作者：
Chi Zhang;Min Ji;S. Ji;Y. An
中科院分区：
文献类型：
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作者：
Chi Zhang;Min Ji;S. Ji;Y. An
用溶剂热法合成了新的硫代锑酸铜（Ⅲ）和硫代砷酸铜（Ⅲ）Rb_2Cu_2Sb_2S_5（1），Cs_2Cu_2Sb_2S_5（2）和Rb_8Cu_6As_8S_19（3）。化合物1含有[Cu 2SbS 3]网，[Sb 2S 4]链通过Cu-S键和Sb-Cu相互作用附着到[Cu 2SbS 3]网，以给出层状结构。在化合物2中，该层由通过二聚[Sb 2S 5]单元连接的共边四面体CuS 4链形成。化合物3的层状结构是由[Cu 3S 7]部分和二聚[As 2S 5]单元构成的螺旋链构成的，二聚[As 2S 5]单元进一步由四聚[As 4S 9]基团连接。研究了它们的光学和热学性质。
The new copper thioantimonates(III) and thioarsenate(III) Rb2Cu2Sb2S5 (1), Cs2Cu2Sb2S5 (2), and Rb8Cu6As8S19 (3) have been synthesized solvothermally. Compound 1 contains a [Cu2SbS3] net to which [Sb2S4] chains adhere through Cu-S bonds and Sb-Cu interactions to give a layered structure. In compound 2, the layer is formed by edge-sharing tetrahedral CuS4 chains linked by dimeric [Sb2S5] units. The layered structure in compound 3 is constructed by helical chains built from [Cu3S7] moieties and dimeric [As2S5] units which are further connected by tetrameric [As4S9] groups. Their optical and thermal properties have been investigated.