Copper-catalyzed oxidative dehydrogenative coupling of carboxylic acids with H-phosphonates: an efficient and practical approach to acyl phosphate esters
Copper-catalyzed oxidative dehydrogenative coupling of carboxylic acids with H-phosphonates: an efficient and practical approach to acyl phosphate esters
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铜催化羧酸与 H-膦酸酯的氧化脱氢偶联：一种高效且实用的酰基磷酸酯制备方法
DOI：
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发表时间：
2017
影响因子：
5.4
通讯作者：
Li Ya-Min
中科院分区：
文献类型：
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作者：
Fu Hong;Yang Tao;Shang Ji-Qi;Zhou Jia-Li;Sun Meng;Li Ya-Min
研究了铜催化的羧酸与H-膦酸酯的氧化偶联反应。这种转化具有广泛的底物范围和良好的官能团耐受性，提供了一种直接和高效的酰基磷酸酯的途径。提出了反应的可能机理
A copper-catalyzed oxidative dehydrogenative coupling of carboxylic acids with H-phosphonates is developed. This transformation exhibits a wide substrate scope and good functional group tolerance, provides a straightforward and highly efficient access to acyl phosphate esters. A possible mechanism for the reaction is proposed