Liquids with Permanent Macroporosity.
Liquids with Permanent Macroporosity.
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具有永久大孔隙的液体。
DOI：
10.1002/anie.202308150
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发表时间：
2023
期刊：
影响因子：
--
通讯作者：
Egleston BD
中科院分区：
文献类型：
--
作者：
Egleston BD
直到Tao Li及其同事最近发表报告描述了形成具有双微-大孔性的多孔液体的合成策略之前，液态下的永久大孔（>50 nm）才被报道。这是通过生产表面涂覆并通过分散流化的分级多孔颗粒来制备的。表面微孔通过流体相的空间排斥实现永久孔隙。由于大孔（480nm）未占据的大孔，该材料具有相当大的吸水能力（27%w/w）。这也使得能够在吸收水时切换热导率。这些是从多孔固体转化为液态的新特性。
Permanent macropores (>50 nm) had not been reported in the liquid state until a recent report by Tao Li and co‐workers describing a synthetic strategy to form a porous liquid with dual micro‐macroporosity. This is prepared by producing hierarchically porous particles that are surface coated and fluidised by dispersion. Surface micropores enable permanent porosity by steric exclusion of the fluid phase. The material has a considerable water uptake capacity (27 % w/w) due to large (480 nm) unoccupied macropores. This also enables switching of thermal conductivity on uptake of water. These are new properties translated from porous solids to the liquid state.