OBSERVATION OF FULLERENE CONES

OBSERVATION OF FULLERENE CONES
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DOI:
10.1016/0009-2614(94)00167-7
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发表时间:
1994-04-01
影响因子:
2.8
通讯作者:
SATTLER, K
SATTLER, K
中科院分区:
化学4区
文献类型:
--
作者:
GE, MH;SATTLER, K

文献摘要

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通过碳原子在石墨衬底上的气相凝聚,制备了纳米碳锥,并利用扫描隧道显微镜(STM)对其进行了分析。观察到的碳锥长24 nm,底径8 nm。它们都有相同的锥角,几乎等于19度。这是完美石墨锥的五种可能的张角中最小的。锥、管和C_(60)的生长可以由具有不同数量五边形的富勒烯型成核种子引发。
Nanometer-sized carbon cones were generated by vapor condensation of carbon atoms on a graphite substrate and were analyzed by scanning tunneling microscopy (STM), The observed cones are up to 24 nm in length and 8 nm in base diameter. They all have the same cone angle almost-equal-to 19-degrees. This is the smallest among five possible opening angles for perfect graphitic cones. The growth of cones, tubules and C60 may be initiated by fullerene-type nucleation seeds with different number of pentagons.