Cluster synthesis by the reactions of [Cp′2M2S4] with metal complexes (Cp′=Cp and substituted cyclopentadienyl ligands, M=Fe, Ru)
Cluster synthesis by the reactions of [Cp′2M2S4] with metal complexes (Cp′=Cp and substituted cyclopentadienyl ligands, M=Fe, Ru)
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DOI：
10.1016/s0010-8545(99)00194-0
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发表时间：
2000-03
影响因子：
20.6
通讯作者：
M. Okazaki;Masahiko Yuki;Katsuaki Kuge;H. Ogino
中科院分区：
文献类型：
--
作者：
M. Okazaki;Masahiko Yuki;Katsuaki Kuge;H. Ogino
双核过渡金属硫配合物[Cp′2M2S4]（Cp′=Cp和取代的配体）是合成多核过渡金属硫簇合物的优良原料。然而，很少有人知道的多功能性的铁和铼的含配合物。这促使我们研究Cp′2M2S4（M=Fe，Ru）的性质。本文综述了Cp′2M2S4（M=Fe，Ru）与各种过渡金属配合物反应合成同簇和异簇的研究进展。
Dinuclear transition-metal sulfur complexes of the type [Cp′2M2S4] (Cp′=Cp and substituted cyclopentadienyl ligands) have been used as excellent starting materials for building up multinuclear transition-metal sulfur clusters. However, little is known about the versatility of the iron- and ruthenium-containing complexes. This urged us to examine the nature of Cp′2M2S4(M=Fe, Ru). The present review describes the research on homo- and heteronuclear cluster synthesis by the reactions of Cp′2M2S4(M=Fe, Ru) with various transition-metal complexes.