Synthesis of a Wide Range of Thioethers by Indium Triiodide Catalyzed Direct Coupling between Alkyl Acetates and Thiosilanes
Synthesis of a Wide Range of Thioethers by Indium Triiodide Catalyzed Direct Coupling between Alkyl Acetates and Thiosilanes
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DOI：
10.1021/ol300450j
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发表时间：
2012-04-06
期刊：
影响因子：
5.2
通讯作者：
Baba, Akio
中科院分区：
文献类型：
--
作者：
Nishimoto, Yoshihiro;Okita, Aya;Baba, Akio
三碘化铟催化用硫代硅烷取代烷基乙酸酯中的乙酰氧基，可获得多种硫醚。该方法对范围广泛的乙酸酯有效，如伯烷基、仲烷基、叔烷基、烯丙基、苯基和丙炔乙酸酯。
An indium triiodide-catalyzed substitution of the acetoxy group in alkyl acetates with thiosilanes provides access to a variety of thioethers. The method is efficient for a wide scope of acetates such as primary alkyl, secondary alkyl, tertiary alkyl, allylic, benzylic, and propargylic acetates.