A stepwise transition from microporosity to mesoporosity in metal–organic frameworks by thermal treatment

A stepwise transition from microporosity to mesoporosity in metal–organic frameworks by thermal treatment
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DOI：
10.1039/c0sc00320d
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发表时间：
2011
期刊：
Chemical Science
影响因子：
8.4
通讯作者：
Daqiang Yuan;Dan Zhao;D. J. Timmons;Hongcai Zhou
Daqiang Yuan;Dan Zhao;D. J. Timmons;Hongcai Zhou
中科院分区：
化学1区
文献类型：
--
作者：
Daqiang Yuan;Dan Zhao;D. J. Timmons;Hongcai Zhou

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合成了一种具有扭曲部分增强网状结构的镉多功能光纤。在升高的温度下活化揭示了前所未有的从微孔到中孔的逐步过渡。这种热处理可以作为制备介孔MOFs的替代方法。
A Cd MOF with twisted partially augmented the net was synthesized. Activation at increasing temperatures revealed an unprecedented stepwise transition from microporosity to mesoporosity. This thermal treatment may serve as an alternative approach for the preparation of mesoporous MOFs.